Ligand- and oxidation state-dependence of structure of triazenido-bridged complexes with face-to-face and open-book dirhodium cores: MO studies and the crystal structure of [Rh2(µ-CO)(bipy)(dppm)(µ-RNNNR)2][PF6]2·2CH2Cl2(R =p-tolyl)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1992/C3/C39920000143
Reference8 articles.
1. The synthesis of mixed-valence dirhodium carbonyl complexes, and the X-ray crystal structures of [{Rh(CO)(PPh3)(µ-RNNNR)}2] and [{Rh(CO)(PPh3)(µ-RNNNR)}2][PF6](R =p-tolyl)
2. Reduction–oxidation properties of organotransition-metal complexes. Part 30. Triazenido-bridged carbonylrhodium bipyridyl complexes with [Rh2]2+, [Rh2]3+, and [Rh2]4+cores, and the X-ray structures of [Rh2(CO)2(bipy)(µ-RNNNR)2][BF4]·CH2Cl2and [{Rh2I(CO)(bipy)(µ-RNNNR)2}2][PF6]2·2.5CH2Cl2(R =p-tolyl)
3. Asymmetric, redox-active carbonyl complexes with [Rh2]2+, [Rh2]3+, and [Rh2]4+ cores
4. Reduction–oxidation properties of organotransition-metal complexes. Part 26. The synthesis of paramagnetic triazenido- and aryl(1-aryliminoethyl)amido-bridged dirhodium carbonyl derivatives containing the [Rh2]3+core
5. N. J. Dhillon and A. G.Orpen, unpublished results.
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1. Chapter 2 Organometallic Complexes of Polypyridine Ligands IV;Advances in Heterocyclic Chemistry;2009
2. Crescent-Shaped Rhodium(I) Complexes with Bis(o-carboxymethylphenyl)triazenide;Inorganic Chemistry;2004-06-24
3. 9. Rhodium 1992;Coordination Chemistry Reviews;1995-12
4. New synthetic routes to face-to-face and open-book triazenide-bridged dirhodium bipyridyl complexes with the [Rh2]4+ core;Journal of the Chemical Society, Dalton Transactions;1994
5. Synthesis and characterization of triazenido and amidino complexes of nickel and palladium;Polyhedron;1993-05
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