B-α-[AsW9O33]9− polyoxometalates incorporating hexanuclear uranium {U6O8}-like clusters bearing the UIV form or unprecedented mixed valence UIV/UVI involving direct UVIO

B-α-[AsW9O33]9− polyoxometalates incorporating hexanuclear uranium {U6O8}-like clusters bearing the UIV form or unprecedented mixed valence UIV/UVI involving direct UVIO–UIV bonding

Published:2015 Issue:46 Volume:44 Page:19772-19776
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Duval Sylvain¹²³⁴⁵,Sobanska Sophie⁶⁷⁴⁵,Roussel Pascal¹²³⁴⁵,Loiseau Thierry¹²³⁴⁵

Affiliation:

1. Unité de Catalyse et Chimie du Solide (UCCS) – UMR CNRS 8181

2. Université de Lille Nord de France

3. USTL-ENSCL

4. 59652 Villeneuve d'Ascq

5. France

6. Laboratoire de Spectrochimie Infrarouge et Raman (LASIR) – UMR CNRS 8516

7. Université Lille Nord de France

Abstract

Nanosized uranium clusters involving a rare U^VIO–U^IV bonding linkage are stabilized by the B-α-[AsW₉O₃₃] polyanionic unit.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02932E

Reference33 articles.

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4. M. T. Pope and U.Kortz, Encyclopedia of Inorganic and Bioinorganic Chemistry, John Wiley & Sons, Ltd, New York, 2012

5. Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

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