A spectroscopic and ab initio study of the hydrogen peroxide–formic acid complex: hindering the internal motion of H2O2-Reference-Cited by-同舟云学术

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A spectroscopic and ab initio study of the hydrogen peroxide–formic acid complex: hindering the internal motion of H2O2

Published:2018 Issue:33 Volume:20 Page:21345-21351
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Li Leo Yuxiu¹²³⁴,Seifert Nathan A.¹²³⁴,Xie Fan¹²³⁴^ORCID,Heger Matthias¹²³⁴^ORCID,Xu Yunjie¹²³⁴^ORCID,Jäger Wolfgang¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Alberta

3. Edmonton

4. Canada

Abstract

Hydrogen peroxide imprints its chirality onto the H₂O₂–formic acid complex, which results in an asymmetric tunnelling potential.

Funder

Natural Sciences and Engineering Research Council of Canada

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP03342K

Reference75 articles.

1. Hydrogen Peroxide Sensing and Signaling

2. Hydrogen Peroxide: A Signaling Messenger

3. Photochemical Formation of Hydrogen Peroxide in Surface and Ground Waters Exposed to Sunlight

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1. Formic acid stability in different solvents by DFT calculations;Journal of Molecular Modeling;2024-02-12

2. n → π* Interaction Enabling Transient Inversion of Chirality;The Journal of Physical Chemistry Letters;2023-09-27

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