Neutral Mo6Q8-clusters with terminal phosphane ligands – a route to water-soluble molecular units of Chevrel phases-Reference-Cited by-同舟云学术

Neutral Mo6Q8-clusters with terminal phosphane ligands – a route to water-soluble molecular units of Chevrel phases

Published:2022 Issue:5 Volume:46 Page:2218-2223
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Novikova Evgeniya D.¹,Gassan Alena D.¹²,Ivanov Anton A.¹^ORCID,Vorotnikov Yuri A.¹^ORCID,Shestopalov Michael A.¹^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia

2. Novosibirsk State University, 2 Pirogova St., 630090 Novosibirsk, Russia

Abstract

Neutral clusters [{Mo6Q8}(Ph2PC2H4COOH)6] (Q = S or Se) readily dissolve in slightly alkaline water forming a highly stable solution. Compounds are redox-active and demonstrate absorbance in all major regions of the spectra – UV, visible and NIR.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Council on grants of the President of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ05802A

Reference45 articles.

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2. Chevrel phases: Past, present and future

3. Prototype systems for rechargeable magnesium batteries

4. Rechargeable nonaqueous lithium/Mo6S8 battery

5. A fast and stable Li metal anode incorporating an Mo6S8 artificial interphase with super Li-ion conductivity

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