New lanthanoid biphenolate complexes, their further reactivity with trimethylaluminium and catalytic activity for the polymerisation of rac-lactide

Author:

Shephard Angus C. G.1,Ali Safaa H.1,Wang Jun1,Guo Zhifang1,Davies Murray S.1,Deacon Glen B.2ORCID,Junk Peter C.1ORCID

Affiliation:

1. College of Science & Engineering, James Cook University, Townsville, QLD. 4811, Australia

2. School of Chemistry, Monash University, Clayton, Vic, 3800, Australia

Abstract

A series of rare earth biphenolate complexes of the general form [Ln(mbmp)(mbmpH)(thf)3] have been synthesised by redox transmetallation/protolysis (RTP) and assessed for ROP activity of rac-lactide.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

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3. F.Ortu and D. P.Mills , Handbook on the Physics and Chemistry of Rare Earths , 55th edn, 2019

4. Precursors for MOCVD and ALD of Rare Earth Oxides−Complexes of the Early Lanthanides with a Donor-Functionalized Alkoxide Ligand

5. Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters

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