CO2-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by in situ crystallographic analysis and molecular modeling-Reference-Cited by-同舟云学术

CO2-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by in situ crystallographic analysis and molecular modeling

Published:2019 Issue:43 Volume:10 Page:10018-10024
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hazra Arpan¹²³⁴^ORCID,van Heerden Dewald P.¹²³⁴^ORCID,Sanyal Somananda¹²³⁴^ORCID,Lama Prem¹²³⁴^ORCID,Esterhuysen Catharine¹²³⁴^ORCID,Barbour Leonard J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Polymer Science

2. University of Stellenbosch

3. Matieland

4. South Africa

Abstract

A flexible twofold interpenetrated MOF reversibly switches between closed, narrow and large pore forms. In situ crystallographic analysis of a narrow-pore intermediate phase provides a detailed explanation of a plateau observed during desorption.

Funder

National Research Foundation

Stellenbosch University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC04043A

Reference57 articles.

1. The Chemistry and Applications of Metal-Organic Frameworks

2. Functional Porous Coordination Polymers