Fluoride binding by an anionic receptor: tuning the acidity of amide NH groups for basic anion hydrogen bonding and recognition

Author:

Montis Riccardo1234ORCID,Bencini Andrea564ORCID,Coles Simon J.789ORCID,Conti Luca564ORCID,Fusaro Luca101112ORCID,Gale Philip A.131415ORCID,Giorgi Claudia564ORCID,Horton Peter N.789,Lippolis Vito1234ORCID,Mapp Lucy K.7891617ORCID,Caltagirone Claudia1234ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche

2. Università degli Studi di Cagliari

3. 09042 Monserrato (CA)

4. Italy

5. Dipartimento di Chimica ‘Ugo Schiff’ Via della Lastruccia

6. 3-13 50019 Sesto Fiorentino (FI)

7. Chemistry University of Southampton Highfield,

8. Southampton SO17 1BJ

9. UK

10. Université de Namur

11. B-5000 Namur

12. Belgium

13. F11 – School of Chemistry

14. The University of Sydney

15. Australia

16. Johnson Matthey

17. Cambridge CB4 0WE

Abstract

Here we report the first family of bis-amide receptors able to bind fluoride in their anionic form.

Funder

Australian Research Council

Fondazione Banco di Sardegna

Regione Autonoma della Sardegna

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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