Intercepting a transient non-hemic pyridine N-oxide Fe(iii) species involved in OAT reactions-Reference-Cited by-同舟云学术

Intercepting a transient non-hemic pyridine N-oxide Fe(iii) species involved in OAT reactions

Published:2021 Issue:95 Volume:57 Page:12836-12839
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Vo Nhat Tam¹,Herrero Christian¹^ORCID,Guillot Régis¹^ORCID,Inceoglu Tanya¹,Leibl Winfried²^ORCID,Clémancey Martin³^ORCID,Dubourdeaux Patrick³,Blondin Geneviève³^ORCID,Aukauloo Ally¹²^ORCID,Sircoglou Marie¹^ORCID

Affiliation:

1. Université Paris-Saclay, CNRS, Institut de chimie moléculaire et des matériaux d'Orsay, 91405, Orsay, France

2. Institute for integrative Biology of the Cell (I2BC), CEA, CNRS Université Paris-Saclay, 1, UMR 9198, 9119, Gif-sur-Yvette, France

3. Laboratoire de Chimie et Biologie des Métaux, Univ. Grenoble Alpes, CNRS, CEA, IRIG, 17 rue des Martyrs, Grenoble F-38000, France

Abstract

An unprecedented pyridine-N-oxide Fe(iii) intermediate has been detected as a potent oxidizing species for catalytic OAT reactions.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04521K

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2. High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

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4. Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions

5. A Theory for Bioinorganic Chemical Reactivity of Oxometal Complexes and Analogous Oxidants: The Exchange and Orbital-Selection Rules

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