Towards metal-free supported quaternary ammonium halide catalysts for an optimized cycloaddition of CO2 onto styrene oxide

Author:

Alonso de la Peña Miguel1,Balas Matthieu23,Kong Julie23,Villanneau Richard2ORCID,Christ Lorraine1,Tuel Alain1ORCID,Launay Franck3ORCID

Affiliation:

1. Université de Lyon, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR CNRS 5256, Université Claude Bernard Lyon 1, 2 av. Einstein, 69626 Villeurbanne Cedex, France

2. Institut Parisien de Chimie Moléculaire, CNRS UMR 8232, Sorbonne Université, Campus Pierre et Marie Curie, 4 Place Jussieu, F-75005 Paris, France

3. Laboratoire de réactivité de surface, UMR CNRS 7197, Sorbonne Université, Campus Pierre et Marie Curie, 4 Place Jussieu, F-75005 Paris, France

Abstract

Quaternary ammonium salts covalently immobilized on mesoporous silica were found efficient catalysts for CO2 cycloaddition onto styrene oxide under various conditions, including solvent-free conditions and/or in the absence of metal catalysts.

Funder

Sorbonne Université

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université Claude Bernard Lyon 1

Publisher

Royal Society of Chemistry (RSC)

Reference43 articles.

1. Global Carbon Budget 2022

2. Growth in emission transfers via international trade from 1990 to 2008

3. P.Glen , How much carbon dioxide can we emit? , 2017 , Published online at https://cicero.oslo.no/en/articles/how-much-carbon-dioxide-can-we-emit , CICERO

4. H.Ritchie , M.Roser and P.Rosado , CO 2 and Greenhouse Gas Emissions, 2020 , Published online at https://ourworldindata.org/co2-and-greenhouse-gas-emissions

5. B.Durand , Captage et stockage du gaz carbonique (CSC), NCL Collect. Store , 2011 , pp. 1–32 , Published online at https://inis.iaea.org/collection/NCLCollectionStore/_Public/43/009/43009426.pdf

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