Heteroleptic Cu(ii) saccharin complexes: intriguing coordination modes and properties

Author:

Mazzone Gloria1234ORCID,Sicilia Emilia1234ORCID,Szerb Elisabeta I.5678ORCID,La Deda Massimo9101112ORCID,Ricciardi Loredana1234ORCID,Furia Emilia1234,Mendiguchia Barbara Sanz9101112,Scarpelli Francesca9101112ORCID,Crispini Alessandra9101112,Aiello Iolinda9101112ORCID

Affiliation:

1. Dipartimento di Chimica e Tecnologie Chimiche

2. Università della Calabria

3. 87036 Arcavacata di Rende

4. Italy

5. “Coriolan Dragulescu” Institute of Chemistry

6. Romanian Academy

7. 300223 Timisoara

8. Romania

9. MAT-InLAB

10. LASCAMM CR-INSTM

11. Unità INSTM della Calabria

12. CNR NANOTEC-Istituto di Nanotecnologia U.O.S. Cosenza

Abstract

A new Cu(ii) O,S-coordinated saccharinate complex is reported, showing crystallochromism and NIR emission in the solid state, in silico ligand exchange reactions with N/S-donor ligands in the presence of model molecules mimicking biological targets.

Funder

Ministero dell'Istruzione, dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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