Crystal facet effects of platinum single-atom catalysts in hydrolytic dehydrogenation of ammonia borane

Author:

Sun Qingdi1,Wang Xuyu2,Wang Hao1,Zhang Hao1,He Qian1ORCID,Zhang Ying1,Cheng Yujie1,Zhang Xingcong1,Shi Shaolin3,Tao Leiming4,He Xiaohui15ORCID,Ji Hongbing135ORCID

Affiliation:

1. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, Guangdong, China

2. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, China

3. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China

4. School of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China

5. Huizhou Research Institute of Sun Yat-sen University, Huizhou 516216, China

Abstract

More electron depletion of the Pt center of the Pt1/Co3O4-c surface facilitates overall electron transfer from the B atom to the ammonia borane (AB) molecule, which ensures the highest activity among Pt1/Co3O4-x in the hydrolytic dehydrogenation of AB reaction.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Guangdong Provincial Pearl River Talents Program

Basic and Applied Basic Research Foundation of Guangdong Province

Natural Science Foundation of Guangdong Province

Natural Science Foundation of Guangdong Province for Distinguished Young Scholars

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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