Synthesis, structure and DFT calculations of 1,2-N-substituted o-carboranes-Reference-Cited by-同舟云学术

Synthesis, structure and DFT calculations of 1,2-N-substituted o-carboranes

Published:2019 Issue:21 Volume:48 Page:7242-7248
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pang Ronglin¹²³,Li Junxia¹²³,Cui Zhongzheng¹²³,Zheng Cheng¹²³,Li Zhifang¹²³^ORCID,Chen Weifeng¹²³,Qi Fan¹²³,Su Li¹²³,Xiao Xu-Qiong¹²³^ORCID

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education

2. Hangzhou Normal University

3. China

Abstract

A series of 1,2-N-substituted o-carboranes were obtained. Ultra-long C–C distances were found in the secondary-amino o-carboranes 3. The relationship between C–C bond lengths and the electron effects of the benzyl groups was discussed.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

China Postdoctoral Science Foundation

Hangzhou Normal University

Deutsche Forschungsgemeinschaft

Niedersächsisches Ministerium für Wissenschaft und Kultur

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04877K

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4. Dicarba-closo-dodecaboranes C2B10H12 and their derivatives

5. Construction of M–M bonds in late transition metal complexes

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