Peroxomolybdate@MOFs as effective catalysts for oxidative desulfurization of fuels: correlation between MOF structure and catalytic activity

Author:

Gao Yan12,Granadeiro Carlos M.1ORCID,Cunha-Silva Luís2ORCID,Zhao Jianshe2ORCID,Balula Salete S.1ORCID

Affiliation:

1. REQUIMTE/LAQV & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal

2. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science, Northwest University, Xi'an, Shaanxi 710127, China

Abstract

The highly active peroxomolybdate, TBA3{PO4[MoO(O2)2]4}·3H2O was incorporated for the first time in various porous MOF support structures (MIL-101, MOF-808, and ZIF-8) to form heterogeneous catalysts with different structural properties.

Funder

National Natural Science Foundation of China

China Scholarship Council

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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