A CoMoO4–Co2Mo3O8 heterostructure with valence-rich molybdenum for a high-performance hydrogen evolution reaction in alkaline solution

Author:

Liu Zheng12345,Zhan Changhong12345,Peng Linkai12345,Cao Yang12345,Chen Yong12345ORCID,Ding Shujiang67895,Xiao Chunhui67895ORCID,Lai Xiaoyong101112135ORCID,Li Jianwei1415165,Wei Songrui1415165ORCID,Wang Jieqiong12345ORCID,Tu Jinchun12345ORCID

Affiliation:

1. State Key Laboratory of Marine Resource Utilization in South China Sea

2. School of Materials Science and Engineering

3. Hainan University

4. Haikou 570228

5. P. R. China

6. Department of Applied Chemistry

7. School of Science

8. Xi'an Jiaotong University

9. Xi'an 710049

10. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering

11. College of Chemistry and Chemical Engineering

12. Ningxia University

13. Yinchuan 750021

14. College of Physics and Optoelectronic Engineering

15. Shenzhen University

16. Shenzhen

Abstract

The heterostructure CoMoO4–Co2Mo3O8 was prepared by a two-step method, including hydrothermal synthesis of CoMoO4 nanowire and subsequent hydrogen reduction treatment of CoMoO4. Due to hierarchical nanostructures of CoMoO4–Co2Mo3O8 facilitated intrinsic activity and conductivity, the outstanding performance for HER, surpassing most cobalt–molybdenum bimetal oxide.

Funder

National Natural Science Foundation of China

Key Research and Development Project of Hainan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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