Heterobimetallic complexes with highly flexible 1,1′-bis(phospholanoalkyl)ferrocene ligands
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. Faculty of Chemistry and Mineralogy
3. Universität Leipzig
4. 04103 Leipzig
5. Germany
Abstract
Flexible 1,1′-bis(phospholanoalkyl)ferrocenes react selectively with platinum(ii), gold(i) and rhodium(i) to give macrocyclic chelate complexes.
Funder
Studienstiftung des Deutschen Volkes
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02567B
Reference66 articles.
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2. A. Togni and T.Hayashi, Ferrocenes. Homogeneous Catalysis. Organic Synthesis. Material Science, VCH, New York, Weinheim, 1995
3. Ligating ability of 1,1′-bis(diphenylphosphino)ferrocene: a structural survey (1994–1998)
4. 1,1'-Bis(alkylarylphosphino)ferrocenes: synthesis, metal complex formation, and crystal structure of three metal complexes of Fe(.eta.5-C5H4PPh2)2
5. Group 10 metal compounds of 1,1′-bis(diphenylphosphino)ferrocene (dppf) and 1,1′-bis(diphenylphosphino)ruthenocene: a structural and electrochemical investigation. X-ray structures of [MCl2(dppr)] (M=Ni, Pd)
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