Anisotropy of CoII transferred to the Cr7Co polymetallic cluster via strong exchange interactions

Author:

Garlatti Elena1234ORCID,Guidi Tatiana5678ORCID,Chiesa Alessandro12349,Ansbro Simon101112138,Baker Michael L.1014158,Ollivier Jacques161718,Mutka Hannu161718,Timco Grigore A.101112138ORCID,Vitorica-Yrezabal Inigo101112138,Pavarini Eva919202122,Santini Paolo1234,Amoretti Giuseppe1234,Winpenny Richard E. P.101112138ORCID,Carretta Stefano1234ORCID

Affiliation:

1. Dipartimento di Scienze Matematiche, Fisiche e Informatiche

2. Università di Parma

3. I-43124 Parma

4. Italy

5. ISIS Facility

6. Rutherford Appleton Laboratory

7. OX11 0QX Didcot

8. UK

9. Institute for Advanced Simulation

10. The School of Chemistry

11. Photon Science Institute

12. The University of Manchester

13. M13 9PL Manchester

14. The University of Manchester at Harwell

15. Didcot

16. Institut Laue-Langevin

17. Grenoble Cedex 9 F-38042

18. France

19. Forschungszentrum Jülich

20. 52425 Jülich

21. Germany

22. JARA High-Performance Computing

Abstract

In the Cr7Co model-system the anisotropy of CoII is effectively transferred to the whole cluster through strong and anisotropic exchange interactions.

Funder

Consiglio Nazionale delle Ricerche

Engineering and Physical Sciences Research Council

Ministry of Education, Universities and Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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