Palladium(0)-catalyzed C(sp3)–Si bond formation via formal carbene insertion into a Si

Palladium(0)-catalyzed C(sp3)–Si bond formation via formal carbene insertion into a Si–H bond

Published:2018 Issue:81 Volume:54 Page:11419-11422
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Zhenxing¹²³⁴⁵,Huo Jingfeng¹²³⁴⁵,Fu Tianren¹²³⁴⁵,Tan Haocheng¹²³⁴⁵,Ye Fei¹²³⁴⁵,Hossain Mohammad Lokman¹²³⁴⁵,Wang Jianbo¹²³⁴⁵^ORCID

Affiliation:

1. Beijing National Laboratory of Molecular Sciences (BNLMS)

2. Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education

3. College of Chemistry

4. Peking University

5. Beijing 100871

Abstract

Pd(0)-Catalyzed formal carbene insertion into Si–H bonds has been achieved as an efficient method for C(sp³)–Si bond formation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC06768F

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