Rare, hypodentate L-κS coordination mode of N,N-dialkyl-N′-aroylthioureas leads to unprecedented mixed-ligand [Pt(phen)(L-κS)2] complexes-Reference-Cited by-同舟云学术

Rare, hypodentate L-κS coordination mode of N,N-dialkyl-N′-aroylthioureas leads to unprecedented mixed-ligand [Pt(phen)(L-κS)2] complexes

Published:2017 Issue:24 Volume:41 Page:14995-15002
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kotzé Izak A.¹²³⁴⁵^ORCID,Smith Vincent J.⁶⁷⁸⁵^ORCID,Kangara Edmore F.¹²³⁴⁵,Koch Klaus R.⁶⁷⁸⁵^ORCID

Affiliation:

1. Molecular Sciences Institute

2. School of Chemistry

3. University of the Witwatersrand

4. Johannesburg

5. South Africa

6. Department of Chemistry and Polymer Science

7. Stellenbosch University

8. Matieland

Abstract

Unprecedented [Pt(phen)(L¹-κS)₂] complexes with two N,N-dibutyl-N′-1-naphthoyl-thioureato molecules coordinated in a rare, hypodentate (L-κS)⁻ mode, stabilised by intra-molecular π–cation type stacking have been isolated. In contrast N,N-diethyl-N′-pivaloyl-thiourea, binds in a bidentate (L-κS,O) mode to give the [Pt(phen)(L³-κS,O)]⁺ species, the [Pt(phen)(L³-κS)₂] complex being unstable.

Funder

National Research Foundation

Universiteit Stellenbosch

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ03178E

Reference42 articles.

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