Comment on “Metal–organic green dye: chemical and physical insight into a modified Zn-benzoporphyrin for dye-sensitized solar cells” by G. Zanotti, N. Angelini, G. Mattioli, A. M. Paoletti, G. Pennesi, G. Rossi, D. Caschera, L. de Marcoc and G. Giglide, RSC Adv., 2016, 6, 5123
Author:
Affiliation:
1. Department of Chemistry
2. University of Saskatchewan
3. Saskatoon
4. Canada S7N5C9
Abstract
The emission spectroscopy and photophysics reported in the title paper are shown to be untenable in light of previously reported experimental results and widely accepted theories of electronic excited state relaxation.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA00213D
Reference6 articles.
1. Metal–organic green dye: chemical and physical insight into a modified Zn-benzoporphyrin for dye-sensitized solar cells
2. Concerning correct and incorrect assignments of Soret (S2–S0) fluorescence in porphyrinoids: a short critical review
3. Photophysics of Soret-Excited Tetrapyrroles in Solution. II. Effects of Perdeuteration, Substituent Nature and Position, and Macrocycle Structure and Conformation in Zinc(II) Porphyrins
4. M.Gouterman in The Porphyrins , ed. D. Dolphin , Academic Press , New York , 1978 , vol. III
5. Exceptional Electronic Modulation of Porphyrins through meso-Arylethynyl Groups. Electronic Spectroscopy, Electronic Structure, and Electrochemistry of [5,15-Bis[(aryl)ethynyl]- 10,20-diphenylporphinato]zinc(II) Complexes. X-ray Crystal Structures of [5,15-Bis[(4‘-fluorophenyl)ethynyl]- 10,20-diphenylporphinato]zinc(II) and 5,15-Bis[(4‘-methoxyphenyl)ethynyl]-10,20-diphenylporphyrin
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