Oligoamylose-entwined porphyrin: excited-state induced-fit for chirality induction-Reference-Cited by-同舟云学术

Oligoamylose-entwined porphyrin: excited-state induced-fit for chirality induction

Published:2016 Issue:12 Volume:52 Page:2481-2484
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Morisue Mitsuhiko¹²³⁴,Yumura Takashi⁵²³⁴,Sawada Risa⁶⁷⁸⁹⁴,Naito Masanobu¹⁰¹¹⁴,Kuroda Yasuhisa¹²³⁴,Chujo Yoshiki⁶⁷⁸⁹⁴

Affiliation:

1. Faculty of Molecular Chemistry and Engineering

2. Kyoto Institute of Technology

3. Kyoto 606-8585

4. Japan

5. Faculty of Material Science and Engineering

6. Department of Polymer Chemistry

7. Graduate School of Engineering

8. Kyoto University

9. Kyoto 615-8510

10. National Institute for Materials Science

11. Ibaraki

Abstract

An oligoamylose-strapped porphyrin displayed circularly polarized luminescence (CPL) in the S₁ state despite being silent in circular dichroism (CD) in the ground state, suggesting chirality induction in the photoexcited porphyrin moiety from the oligoamylose-strap in the photoexcited state.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC08488A

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