Oxidative dehydrogenation of cyclohexene on atomically precise subnanometer Cu4−nPdn (0 ≤ n ≤ 4) tetramer clusters: the effect of cluster composition and support on performance-Reference-Cited by-同舟云学术

Oxidative dehydrogenation of cyclohexene on atomically precise subnanometer Cu_4−nPd_n (0 ≤ n ≤ 4) tetramer clusters: the effect of cluster composition and support on performance

Published:2023 Issue: Volume:242 Page:70-93
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Jašík Juraj¹^ORCID,Valtera Stanislav¹^ORCID,Vaidulych Mykhailo¹^ORCID,Bunian Muntaseer²^ORCID,Lei Yu²^ORCID,Halder Avik³^ORCID,Tarábková Hana⁴^ORCID,Jindra Martin⁴⁵^ORCID,Kavan Ladislav⁴^ORCID,Frank Otakar⁴^ORCID,Bartling Stephan⁶^ORCID,Vajda Štefan¹^ORCID

Affiliation:

1. Department of Nanocatalysis, J. Heyrovský Institute of Physical Chemistry v.v.i., Czech Academy of Sciences, Dolejškova 2155/3, 182 23 Prague 8, Czech Republic

2. Department of Chemical and Materials Engineering, The University of Alabama in Huntsville, Huntsville, Alabama 35899, USA

3. Materials Science Division, Argonne National Laboratory, 9600 South Cass Avenue, Lemont, Illinois 60439, USA

4. Department of Electrochemical Materials, J. Heyrovský Institute of Physical Chemistry v.v.i., Czech Academy of Sciences, Dolejškova 2155/3, 182 23 Prague 8, Czech Republic

5. Department of Physical Chemistry, University of Chemistry and Technology in Prague, Technická 5, 166 28 Prague, Czech Republic

6. Leibniz Institute for Catalysis (LIKAT), Albert-Einstein-Strasse 29a, D-18059 Rostock, Germany

Abstract

High fidelity selectivity tuning of the oxidative dehydrogenation of cyclohexene was achieved through the control of the atomic composition of CuPd clusters and their interactions with the support.

Funder

European Regional Development Fund

U.S. Department of Energy

Deutscher Akademischer Austauschdienst

Horizon 2020 Framework Programme

National Science Foundation

Alabama EPSCoR

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

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