Oxidative addition of arsenic halides to platinum(0)-Reference-Cited by-同舟云学术

Oxidative addition of arsenic halides to platinum(0)

Published:2019 Issue:11 Volume:48 Page:3547-3550
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Muessig Jonas H.¹²³⁴⁵,Stennett Tom E.¹²³⁴⁵,Schmidt Uwe¹²³⁴⁵,Dewhurst Rian D.¹²³⁴⁵,Mailänder Lisa¹²³⁴⁵,Braunschweig Holger¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

Abstract

AsCl₃ and AsBr₃ are shown to undergo oxidative addition to Pt(0) complexes. With AsCl₃, a single As–Cl oxidative addition step selectively yields (chloro)(arsenido)-Pt(ii) complexes, whereas with AsBr₃ both monomeric and cluster compounds are produced.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04995E

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