Doubly fused N,N,N-iron ethylene polymerization catalysts appended with fluoride substituents; probing catalytic performance via a combined experimental and MLR study-Reference-Cited by-同舟云学术

Doubly fused N,N,N-iron ethylene polymerization catalysts appended with fluoride substituents; probing catalytic performance via a combined experimental and MLR study

Published:2021 Issue:13 Volume:11 Page:4605-4618
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Zhang Qiuyue¹²³⁴⁵,Yang Wenhong¹²³⁴^ORCID,Wang Zheng¹²³⁴,Solan Gregory A.¹²³⁴⁶^ORCID,Liang Tongling¹²³⁴^ORCID,Sun Wen-Hua¹²³⁴⁶^ORCID

Affiliation:

1. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences

2. Institute of Chemistry, Chinese Academy of Sciences

3. Beijing 100190

4. China

5. CAS Research/Education Center for Excellence in Molecular Sciences and International School

6. Department of Chemistry

Abstract

In agreement with the MLR analysis, the fluorinated iron precatalyst, R¹ = F, R² = R³ = CH(p-FPh)₂, proved the most active at 70 °C generating strictly linear polyethylene waxes.

Funder

National Natural Science Foundation of China

Institute of Chemistry, Chinese Academy of Sciences

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00821H

Reference106 articles.

1. Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes