Intraprotein transmethylation via a CH3–Co(iii) species in myoglobin reconstituted with a cobalt corrinoid complex-Reference-Cited by-同舟云学术

Intraprotein transmethylation via a CH3–Co(iii) species in myoglobin reconstituted with a cobalt corrinoid complex

Published:2016 Issue:8 Volume:45 Page:3277-3284
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Morita Yoshitsugu¹²³⁴⁵,Oohora Koji¹²³⁴⁵,Sawada Akiyoshi⁶⁷⁸⁵,Doitomi Kazuki⁶⁷⁸⁵,Ohbayashi Jun¹²³⁴⁵,Kamachi Takashi⁶⁷⁸⁵,Yoshizawa Kazunari⁶⁷⁸⁵⁹,Hisaeda Yoshio¹⁰²⁷⁸⁵,Hayashi Takashi¹²³⁴⁵

Affiliation:

1. Department of Applied Chemistry

2. Graduate School of Engineering

3. Osaka University

4. Suita 565-0871

5. Japan

6. Institute for Materials Chemistry and Engineering and International Research Centre for Molecular Systems

7. Kyushu University

8. Fukuoka 819-0395

9. Elements Strategy Initiative for Catalysts and Batteries (ESICB)

10. Department of Chemistry and Biochemistry

Abstract

A cobalt corrinoid complex bound in the myoglobin heme pocket demonstrates the formation of a CH₃–Co(iii) bond and subsequent transmethylation.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04109K

Reference61 articles.

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5. Chemistry and Enzymology of Vitamin B12

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