Cobalt-catalysed unactivated C(sp3)–H amination: two-state reactivity and multi-reference electronic character-Reference-Cited by-同舟云学术

Cobalt-catalysed unactivated C(sp3)–H amination: two-state reactivity and multi-reference electronic character

Published:2019 Issue:8 Volume:9 Page:1879-1890
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Yu Yang¹²³⁴⁵,Luo Gen¹²³⁴⁵^ORCID,Yang Jimin¹²³⁴⁵,Luo Yi¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Chemical Engineering

3. Dalian University of Technology

4. Dalian 116024

5. China

Abstract

A remarkable two-state reactivity scenario and an unusual multi-reference character have been computationally found in Co-catalysed C(sp³)–H amination. In addition, the investigation on the additive, aminating reagent, metal center, and auxiliary ligand provides implications for development of new catalytic C–H functionalization systems.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CY/C9CY00239A

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