Brominated [20]silafulleranes: pushing the limits of steric loading-Reference-Cited by-同舟云学术

Brominated [20]silafulleranes: pushing the limits of steric loading

Published:2023 Issue:48 Volume:59 Page:7459-7462
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bamberg Marcel¹^ORCID,Gasevic Thomas²^ORCID,Bolte Michael¹^ORCID,Virovets Alexander¹^ORCID,Lerner Hans-Wolfram¹^ORCID,Grimme Stefan²^ORCID,Bursch Markus³^ORCID,Wagner Matthias¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt am Main, Max-von-Laue-Straße 7, 60438 Frankfurt am Main, Germany

2. Mulliken Center for Theoretical Chemistry, Clausius-Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstraße 4, 53115 Bonn, Germany

3. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

Abstract

Treatment of the [20]silafullerane [nBu4N][Cl@Si20(SiH3)12H8] with BBr3 enables the synthesis of regioselectively H/Br-substituted [nBu4N][Cl@Si20(SiBr2H)12Br8] and perbrominated [nBu4N][Cl@Si20(SiBr3)12Br8], depending on the reaction conditions.

Funder

Deutsche Forschungsgemeinschaft

Max-Planck-Gesellschaft

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02142D

Reference37 articles.

1. One-Step Synthesis of a [20]Silafullerane with an Endohedral Chloride Ion

2. [Cl@Si20H20]−: Parent Siladodecahedrane with Endohedral Chloride Ion

3. Regioselective Derivatization of Silylated [20]Silafulleranes

4. Silicon chemistry in zero to three dimensions: from dichlorosilylene to silafullerane

5. Polyhedral Compounds of the Heavier Group 14 Elements: Silicon, Germanium, Tin, and Lead

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