Five-coordinate transition metal complexes and the value of τ5: observations and caveats-Reference-Cited by-同舟云学术

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Five-coordinate transition metal complexes and the value of τ5: observations and caveats

Published:2020 Issue:42 Volume:49 Page:14798-14806
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Blackman Allan G.¹²³⁴⁵^ORCID,Schenk Elaine B.⁶⁷⁸⁹,Jelley Rebecca E.¹⁰¹¹⁵¹²,Krenske Elizabeth H.¹³⁷⁸⁹,Gahan Lawrence R.¹³⁷⁸⁹

Affiliation:

1. Department of Chemistry

2. Centre for Biomedical and Chemical Sciences

3. School of Science

4. Auckland University of Technology

5. Auckland 1142

6. School of Mathematics and Physics

7. The University of Queensland

8. Brisbane

9. Australia

10. School of Chemical Sciences

11. University of Auckland

12. New Zealand

13. School of Chemistry and Molecular Biosciences

Abstract

The τ₅ parameter is not limited to values between 0 and 1 in five-coordinate transition metal complexes.

Funder

University of Queensland

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02985H

Reference65 articles.

1. Trigonal prismatic vs. octahedral stereochemistry in complexes derived from innocent ligands

2. Structure of tris(ethylenediamine)chromium(III) pentacyanonickelate(II) sesquihydrate, [Cr(NH2CH2CH2NH2)3] [Ni(CN)5].1. 5H2O

3. Structural motifs and topological representation of Mn coordination clusters

4. Single-crystal ESR spectra of copper(II) complexes with geometries intermediate between a square pyramid and a trigonal bipyramid

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