Bridging the opposite chemistries of tantalum and tungsten polyoxometalates

Abstract

Reaction of Ta peroxometalate and tungstate affords the first systematic series of Ta/W isopolyoxometalates. An analogous reaction system yields a Nb/W cluster. The electronic structure and stability of these clusters varies as a function of the group V metal content, as inferred from spectroscopic, electrochemical and mass-spectrometry analysis and confirmed by DFT calculations.