An insight into triel bonds in O,O′-diarylphosphorodithioates of thallium(i): experimental and theoretical investigations

Author:

Firdoos Tahira1,Kumar Pretam1ORCID,Radha Anu1,Gomila Rosa M.2ORCID,Frontera Antonio2ORCID,Sood Puneet3,Pandey Sushil K.1ORCID

Affiliation:

1. Post Graduate Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu Tawi-180006, J&K, India

2. Departament de Química, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), Spain

3. Advanced Materials Research Center, Indian Institute of Technology, Block-A2 Building, Kamand Campus, Mandi, Himachal Pradesh-175005, India

Abstract

Two new thallium(i) compounds have been synthesized and structurally characterized. The existence of triel bonds in these compounds has been confirmed by HSA and DFT calculations using QTAIM and NCI plot index methods.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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