3- and 4-(α-diazobenzyl)pyridine-N-oxides as photoresponsive magnetic couplers for 2p–4f heterospin systems: formation of carbene–TbIII and carbene–DyIII single-molecule magnets-Reference-Cited by-同舟云学术

3- and 4-(α-diazobenzyl)pyridine-N-oxides as photoresponsive magnetic couplers for 2p–4f heterospin systems: formation of carbene–TbIII and carbene–DyIII single-molecule magnets

Published:2016 Issue:16 Volume:45 Page:7067-7077
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Murashima Kensuke¹²³⁴,Karasawa Satoru¹²³⁴⁵,Yoza Kenji⁶⁷⁴,Inagaki Yuji⁸²³⁴,Koga Noboru¹²³⁴

Affiliation:

1. Graduate School of Pharmaceutical Sciences

2. Kyushu University

3. Fukuoka

4. Japan

5. PRESTO

6. Bruker AXS K.K.

7. Yokohama

8. Department of Applied Quantum Physics

Abstract

Dinuclear Tb^III – and Dy^III – D1pyO complexes were photolyzed to afford heterospin SMMs with U_eff/k_B = 30 and 39 K, respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00420B

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