Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks-Reference-Cited by-同舟云学术

Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks

Published:2016 Issue:45 Volume:45 Page:18094-18097
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Frost Jamie M.¹²³⁴⁵^ORCID,Kettles Fraser J.¹²³⁴⁵,Wilson Claire¹²³⁴⁵^ORCID,Murrie Mark¹²³⁴⁵^ORCID

Affiliation:

1. WestCHEM

2. School of Chemistry

3. University of Glasgow

4. University Avenue

5. Glasgow

Abstract

Use of an aminopolyalcohol-based Mn^II complex in solvothermal Cu^II chemistry leads to a rare example of a high nuclearity heterometallic {MnIII10CuII5} system, in which four {Cu^II(H₁Edte)} units trap an inner {MnIII10Cu^II} oxide core.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03914F

Reference25 articles.

1. Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites

2. Synthesis of 3d Metallic Single-Molecule Magnets

3. Using tripodal alcohols to build high-spin molecules and single-molecule magnets

4. Linking Centered Manganese Triangles into Larger Clusters: A {Mn32} Truncated Cube

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A new {Cu₃–Gd₂} cluster as a two-in-one functional material with unique topology acting as a refrigerant and adsorbent for cationic dye;CrystEngComm;2022

2. Self‐Assembly of a Dodecanuclear [Ni 12 ] Wheel;European Journal of Inorganic Chemistry;2021-02-24

3. From tetranuclear to pentanuclear [Co–Ln] (Ln = Gd, Tb, Dy, Ho) complexes across the lanthanide series: effect of varying sequence of ligand addition;Dalton Transactions;2021

4. Solvent-induced structural transformation from heptanuclear to decanuclear [Co–Ln] coordination clusters: trapping of unique counteranion and understanding of aggregation pathways;Dalton Transactions;2021

5. A novel self-assembled Na{Cu12Zn4} multifunctional material: first report of a discrete coordination compound for detection of Ca2+ions and selective adsorption of cationic dyes in water;Dalton Transactions;2020