Affiliation:
1. Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 59717, USA
Abstract
In the presence of the bulky monophosphine PtBu3, palladium usually prefers to react with Ar–Cl over Ar–OTf bonds. However, strongly coordinating solvents can bind to palladium, inducing a reversal of selectivity.
Funder
Research Corporation for Science Advancement
M.J. Murdock Charitable Trust
Division of Chemistry
Division of Advanced Cyberinfrastructure
Division of Biological Infrastructure
Publisher
Royal Society of Chemistry (RSC)
Reference74 articles.
1. Tutorial on Oxidative Addition
2. J. J.Hartwig , in Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , Sausalito, CA , 2010
3. Reductive Elimination of Aryl Halides from Palladium(II)
4. Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction
5. Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes
Cited by
17 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献