Iron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic use for direct oxidation of sp3 C

Iron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic use for direct oxidation of sp3 C–H bonds

Published:2021 Issue:18 Volume:50 Page:6343-6348
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nishimura Tsubasa¹²³⁴⁵,Sakurai Takahiro¹²³⁴⁵,Shinokubo Hiroshi¹²³⁴⁵^ORCID,Miyake Yoshihiro¹²³⁴⁵^ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Nagoya 464-8603

5. Japan

Abstract

Iron hexamesityl-5,15-diazaporphyrin was successfully synthesized. Its use for catalytic oxidation of cyclooctane showed high performance with a total TON up to 731. The introduction of bulky mesityl groups prevented the catalyst deactivation via formation of a μ-oxo dimer.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00893E

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