A hexacoordinated Bi3+-based ellagate MOF with acid/base resistance boosting carbon dioxide electroreduction to formate

Author:

Li Junjun1,Wang Congyong23,Wang Dingjia4,Yang Chenhuai1,Cui Xiaoya56,Gao Xuejiao J.4ORCID,Zhang Zhicheng1ORCID

Affiliation:

1. Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

2. Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207, China

3. Department of Chemistry, Faculty of Science, National University of Singapore, Singapore 117543, Singapore

4. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

5. Ministry of Education Key Laboratory of Protein Sciences, Beijing Advanced Innovation Center for Structural Biology, School of Life Sciences, Tsinghua University, Beijing 100084, China

6. Beijing Frontier Research Center for Biological Structures, Tsinghua University, Beijing 100084, China

Abstract

Rod-shaped SU-101 catalysts exhibited a high HCOO Faraday efficiency of 93.66% at −1.10 V vs. RHE due to the unique hexacoordinated Bi3+ site of SU-101.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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