31P NMR study of the activated radioprotection mechanism of octylphenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues-Reference-Cited by-同舟云学术

31P NMR study of the activated radioprotection mechanism of octylphenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues

Published:2019 Issue:30 Volume:48 Page:11547-11555
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Horne Gregory P.¹²³⁴^ORCID,Kiddle James J.⁵⁶⁷⁸^ORCID,Zarzana Christopher A.¹²³⁴^ORCID,Rae Cathy¹²³⁴^ORCID,Peller Julie R.⁹⁶¹⁰⁸^ORCID,Cook Andrew R.¹¹⁶¹²⁸^ORCID,Mezyk Stephen P.¹³¹⁴¹⁵⁸^ORCID,Mincher Bruce J.¹²³⁴^ORCID

Affiliation:

1. Idaho National Laboratory

2. Center for Radiation Chemistry Research

3. Idaho Falls

4. 83415, USA

5. Western Michigan University

6. Department of Chemistry

7. Kalamazoo

8. USA

9. Valparaiso University

10. Valparaiso

11. Brookhaven National Laboratory

12. Upton

13. California State University Long Beach

14. Department of Chemistry and Biochemistry

15. Long Beach

Abstract

Complexation of nitric acid by ligands containing conjugated aromatic phosphine oxide functionalities affords activated radioprotection through quenching n-dodecane excited states originating from gamma radiolysis.

Funder

Office of Nuclear Energy

Basic Energy Sciences

Nuclear Energy University Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01950B

Reference63 articles.

1. THE EXTRACTION OF Am(III) FROM NITRIC ACID BY OCTYL(PHENYL)-N,N-DIISOBUTYLCARBAMOYLMETHYLPHOSPHINE OXIDE - TRI-n-BUTYL PHOSPHATE MIXTURES