Unprecedented layered coordination polymers of dithiolene group 10 metals: magnetic and electrical properties

Author:

Delgado Esther1234,Gómez-García Carlos J.564,Hernández Diego1234,Hernández Elisa1234,Martín Avelino1784,Zamora Félix12349

Affiliation:

1. Departamento de Química Inorgánica

2. Universidad Autónoma de Madrid

3. 28049 Madrid

4. Spain

5. Instituto de Ciencia Molecular. Universidad de Valencia. C/Catedrático José Beltrán

6. Valencia

7. Universidad de Alcalá. Campus Universitario

8. Alcalá de Henares

9. Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia)

Abstract

One-pot reactions between Ni(ii), Pd(ii) or Pt(ii) salts and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in KOH medium under argon lead to a series of bis-dithiolene coordination polymers.

Funder

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

1. Metal bis-1,2-dithiolene complexes in conducting or magnetic crystalline assemblies

2. Progress in Inorganic Chemistry, Dithiolene Chemistry: Synthesis, Properties, and Applications, ed. K. D. Karlin and E. I. Stiefel, John Wiley and Sons, New York, 2004, vol. 52

3. U. T. Muller-Westerhoff and B.Vance, in Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon Press, Oxford, 1st edn, 1987, vol. 2

4. The chemistry and solid state properties of nickel, palladium and platinum bis(maleonitriledithiolate) compounds

5. Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere

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