Substituted troponimines: when aromatization of the conjugate acid leads to very strong neutral organic superbases
Author:
Affiliation:
1. Department of Chemistry
2. Faculty of Science
3. Ferdowsi University of Mashhad
4. Mashhad
5. Iran
6. Group for Computational Life Sciences
7. Division of Physical Chemistry
8. Ruder Boskovic Institute
9. 10000 Zagreb
10. Croatia
Abstract
Highly basic 3,6-disubstituted troponimino-scaffolds enable the introduction of new aromatic-stabilizing neutral organic superbase groups.
Funder
Ferdowsi University of Mashhad
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ02349B
Reference51 articles.
1. T. Ishikawa , Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts , 2009
2. Heterocyclic superbases: retrospective and current trends
3. Superbases in the gas phase: Amidine and guanidine derivatives with proton affinities larger than 1000 kj mol−1
4. Consequences of proton transfer in guanidine
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