Synthesis and characterisation of κ2-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation
Author:
Affiliation:
1. Department of Chemistry & Biology
2. Ryerson University
3. Toronto
4. Canada
5. Department of Chemistry
6. University of Toronto
Abstract
Novel Ni(ii) enolate complexes derived from (Z)-1-R-2-(4′,4′-dimethyl-2′-oxazolin-2′-yl)eth-1-en-1-ols are synthesised and structurally examined. The complexes display good potency as olefin polymerisation catalysts.
Funder
Ryerson University
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/RA/C8RA10304F
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5. Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
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1. Synthesis and structural studies of group 12 oxazoline-enolate coordination complexes of (Z)-1-R-2-(4′,4′-dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ates; part I: the zinc derivatives;Canadian Journal of Chemistry;2023-07-01
2. Synthesis, Characterization, and Catalytic Exploration of Mononuclear Mo(VI) Dioxido Complexes of (Z)-1-R-2-(4′,4′-Dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ates;Molecules;2022-02-15
3. Heteroatom Exchange Chemistry in (Z)-1-R-2-(4′,4′-dimethyl)-2′-oxazolin-2′yl)-eth-1-en-1-ols: Access to Chelate-stabilized Thioester Analogues of Dithiooxophosphoranes;Chemistry Letters;2022-02-05
4. Organometallic Iridium Complexes of (Z)-1-Phenyl-2-(4′,4′-dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ate: Structural Aspects, Reactivity and Applications in the Catalytic Dehydrogenation of Alkanes;Bulletin of the Chemical Society of Japan;2021-08-15
5. Divalent cobalt and copper coordination complexes of κ2-N, O-derivatives of (Z)-1-R-2-(2′-oxazolin-2′-yl)-eth-1-en-1-ates: Structure and reactivity patterns;Inorganica Chimica Acta;2021-01
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