Synthesis and reactions of N-heterocycle functionalised variants of heterometallic {Cr7Ni} rings

Author:

Whitehead George F. S.1234,Ferrando-Soria Jesús1234,Carthy Laura1234,Pritchard Robin G.1234,Teat Simon J.5678,Timco Grigore A.1234,Winpenny Richard E. P.1234

Affiliation:

1. School of Chemistry

2. The University of Manchester

3. Manchester M13 9PL

4. UK

5. Advanced Light Source

6. Lawrence Berkeley Laboratory

7. Berkeley

8. USA

Abstract

Here we present a series of linked cage complexes of functionalised variants of the octametallic ring {Cr7Ni} with the general formula [nPr2NH2][Cr7NiF8(O2CtBu)15(O2CR)], where HO2CR is a N-heterocycle containing carboxylic acid.

Funder

Engineering and Physical Sciences Research Council

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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