Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W

Author:

Kobayashi Daiya12345ORCID,Kobayashi Hirokazu56784,Kusada Kohei56784ORCID,Yamamoto Tomokazu91011124,Toriyama Takaaki1311124,Matsumura Syo91011124,Kawaguchi Shogo1415164,Kubota Yoshiki17618194,Haneda Masaaki202122423ORCID,Aspera Susan Meñez2425264ORCID,Nakanishi Hiroshi2425264,Arai Shigebumi1234,Kitagawa Hiroshi56784ORCID

Affiliation:

1. Nippon Soda Co. Ltd

2. Chiba Research Center

3. Ichihara

4. Japan

5. Division of Chemistry

6. Graduate School of Science

7. Kyoto University

8. Kyoto 606-8502

9. Department of Applied Quantum Physics and Nuclear Engineering

10. Graduate School of Engineering

11. Kyushu University

12. Fukuoka 819-0395

13. The Ultramicroscopy Research Center

14. Japan Synchrotron Radiation Research Institute (JASRI)

15. SPring-8

16. Hyogo 679-5198

17. Department of Physical Science

18. Osaka Prefecture University

19. Osaka 599-8531

20. Advanced Ceramics Research Center

21. Nagoya Institute of Technology

22. Tajimi

23. Frontier Research Institute for Materials Science

24. National Institute of Technology

25. Akashi College

26. Akashi

Abstract

We report PtW solid-solution alloy nanoparticles (NPs) as a reverse water-gas shift (RWGS) reaction catalyst for the first time. Atomic-level alloying of Pt and W significantly enhanced the RWGS reaction activity of Pt NPs.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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