Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32−– a unique entry to aryltricyanoborates-Reference-Cited by-同舟云学术

Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32−– a unique entry to aryltricyanoborates

Published:2017 Issue:9 Volume:8 Page:5962-5968
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Landmann Johannes¹²³⁴⁵,Hennig Philipp T.¹²³⁴⁵,Ignat’ev Nikolai V.⁶⁷⁵,Finze Maik¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Institut für nachhaltige Chemie & Katalyse mit Bor (ICB)

3. Julius-Maximilians Universität Würzburg

4. 97074 Würzburg

5. Germany

6. Merck KGaA

7. 64293 Darmstadt

Abstract

S_NAr reactions of the tricyanoboryl dianion B(CN)₃²⁻with selected fluoroarenes and perfluoropyridine resulted in a wealth of new tricyanoarylborate anions in high yields with high chemo- and regioselectivity.

Funder

Merck KGaA

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02249B

Reference59 articles.

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2. Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

3. Creation of Nucleophilic Boryl Anions and Their Properties

4. Modern 1,3,2‐Diazaborole Chemistry – A Metamorphosis from Electrophilic to Nucleophilic Boron

5. Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion

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