Ligand- and Brønsted acid/base-switchable reaction pathways in gold(i)-catalyzed cycloisomerizations of allenoic acids

Author:

Handa Sachin1234,Subramanium Sri S.1234,Ruch Aaron A.12341,Tanski Joseph M.1564,Slaughter LeGrande M.12341

Affiliation:

1. Department of Chemistry

2. Oklahoma State University

3. Stillwater

4. USA

5. Vassar College

6. Poughkeepsie

Abstract

Competing gold-catalyzed cycloisomerizations of γ-allenoic acids are optimized through ligand and Brønsted acid/base effects, affording three distinct classes of lactones.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference123 articles.

1. Gold-Catalyzed Organic Reactions

2. Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

3. Gold-Catalyzed Organic Transformations

4. Modern Gold Catalyzed Synthesis, ed. A. S. K. Hashmi and F. D. Toste, Wiley-VCH, Weinheim, 2012

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