Effects of solvent molecules on hemi-bonded (CH3SH)2+: infrared absorption of [(CH3SH)2–X]+ with X = H2O, (CH3)2CO, or NH3 and (CH3SH)n+ (n = 3–6)-Reference-Cited by-同舟云学术

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Effects of solvent molecules on hemi-bonded (CH3SH)2+: infrared absorption of [(CH3SH)2–X]+ with X = H2O, (CH3)2CO, or NH3 and (CH3SH)n+ (n = 3–6)

Published:2019 Issue:29 Volume:21 Page:16055-16063
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Xie Min¹²³⁴⁵^ORCID,Tsai Huei-Ru¹²³⁴,Fujii Asuka⁶⁷⁸⁹¹⁰^ORCID,Lee Yuan-Pern¹²³⁴¹¹^ORCID

Affiliation:

1. Department of Applied Chemistry and Institute of Molecular Science

2. National Chiao Tung University

3. Hsinchu 30010

4. Taiwan

5. MOE Key Laboratory of Laser Life Science & Institute of Laser Life Science

6. Department of Chemistry

7. Graduate School of Science

8. Tohoku University

9. Sendai 980-8578

10. Japan

11. Center for Emergent Functional Matter Science

Abstract

The (3e-2c)-bonded (CH₃SH)₂⁺ structure is preserved when H₂O, (CH₃)₂CO, or CH₃SH binds, but becomes broken by NH₃ because of proton transfer.

Funder

Japan Society for the Promotion of Science

Ministry of Science and Technology, Taiwan

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03158H

Reference35 articles.

1. Hydroxyl radical induced decarboxylation of amino acids. Decarboxylation vs bond formation in radical intermediates

2. Side Chain Fragmentation of N-Terminal Threonine or Serine Residue Induced through Intramolecular Proton Transfer to Hydroxy Sulfuranyl Radical Formed at Neighboring Methionine in Dipeptides

3. Very Stable Ribonucleotide Substrate Radical Relevant for Class I Ribonucleotide Reductase

4. Aromatic Residues Regulating Electron Relay Ability of S-Containing Amino Acids by Formations of S∴π Multicenter Three-Electron Bonds in Proteins

5. Effects of ship emissions on sulphur cycling and radiative climate forcing over the ocean

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