Flipping of the coordinated triazine moiety in Cu(i)–L2and the small electronic factor, κel, for direct outer-sphere cross reactions: syntheses, crystal structures and redox behaviour of copper(ii)/(i)–L2complexes (L = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine)-Reference-Cited by-同舟云学术

Flipping of the coordinated triazine moiety in Cu(i)–L2and the small electronic factor, κel, for direct outer-sphere cross reactions: syntheses, crystal structures and redox behaviour of copper(ii)/(i)–L2complexes (L = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine)

Published:2015 Issue:31 Volume:44 Page:13979-13990
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yamada Atsutoshi¹²³⁴,Mabe Takuya¹²³⁴,Yamane Ryohei¹²³⁴,Noda Kyoko¹²³⁴,Wasada Yuko⁵⁶⁷⁴,Inamo Masahiko⁸⁹¹⁰⁴,Ishihara Koji¹¹¹²¹³⁴,Suzuki Takayoshi⁸¹⁴¹⁵¹⁶,Takagi Hideo D.¹²³⁴

Affiliation:

1. Research Center for Materials Science

2. Nagoya University

3. Nagoya 464-8602

4. Japan

5. Department of Chemical Engineering

6. Nagoya Institute of Technology

7. Nagoya 466-8555

8. Department of Chemistry

9. Aichi University of Education

10. Kariya 448-8542

11. School of Science and Engineering

12. Waseda University

13. Tokyo 169-8555

14. Okayama University

15. Okayama

16. 700-8530 Japan

Abstract

Flipping of the triazine ring of the coordinated pdt ligand was observed, and the non-adiabaticity factorκ_elfor direct cross reactions was estimated asca.10⁻⁷.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01808K

Reference39 articles.

1. Energised (entatic) States of Groups and of Secondary Structures in Proteins and Metalloproteins

2. D. E. Fenton , Biocoordination Chemistry, Oxford Science Publications, 1995, ch. 1, pp. 4–9

3. Metalloenzymes: the entatic nature of their active sites.

4. D. B. Rorabacher

5. Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+and five-coordinate [CuL2(solvent)]2+complexes (L = 6,6′-dimethyl-2,2′-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+in nitromethane

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Electron Transfer Reactions in Solution;Metal Ions and Complexes in Solution;2023-12-04

2. In vitro biological and in silico molecular docking and ADME studies of a substituted triazine-coordinated cadmium(II) ion: efficient cytotoxicity, apoptosis, genotoxicity, and nuclease-like activity plus binding affinity towards apoptosis-related proteins;BioMetals;2022-04-02

3. 1,2,4-Triazines and Their Benzo Derivatives;Comprehensive Heterocyclic Chemistry IV;2022

4. Synthesis, structures, DNA-binding, cytotoxicity and molecular docking of CuBr(PPh3)(diimine);Polyhedron;2020-12

5. A Modified Synthesis of 6-Aryl-3-(6-R-pyridin-2-yl)-1,2,4-triazines;Russian Journal of Organic Chemistry;2018-10