Characterization of decavanadate and decaniobate solutions by Raman spectroscopy

Author:

Aureliano Manuel12345,Ohlin C. André6789,Vieira Michele O.510114,Marques M. Paula M.51011412ORCID,Casey William H.10131415,Batista de Carvalho Luís A. E.510114ORCID

Affiliation:

1. FCT and CCmar

2. University of Algarve

3. 8005-139 Faro

4. Portugal

5. Unidade de I&D Química-Física Molecular

6. School of Chemistry

7. Monash University

8. Clayton

9. Australia

10. Department of Chemistry

11. University of Coimbra

12. Department of Life Sciences

13. University of California

14. Davis

15. USA

Abstract

V10 dissociates at most pH values into smaller tetrahedral vanadate oligomers such as V4 and V2, whereas Nb10 dissociates into Nb6 under mildly or highly alkaline conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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