Stabilization of MIV = Ti, Zr, Hf, Ce, and Th using a selenium bis(phenolate) ligand-Reference-Cited by-同舟云学术

Stabilization of MIV = Ti, Zr, Hf, Ce, and Th using a selenium bis(phenolate) ligand

Published:2015 Issue:6 Volume:44 Page:2693-2702
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Behrle Andrew C.¹²³⁴,Levin Jessica R.⁵¹⁶⁷⁴,Kim Jee Eon⁵¹⁶⁷⁴^ORCID,Drewett Jonathan M.¹²³⁴,Barnes Charles L.¹²³⁴,Schelter Eric J.⁵¹⁶⁷⁴,Walensky Justin R.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Missouri-Columbia

3. Columbia

4. USA

5. P. Roy and Diana T. Vagelos Laboratories

6. University of Pennsylvania

7. Philadelphia

Abstract

We report M(iv) M = Ti, Zr, Hf, Ce, and Th, complexes of a selenium bis(phenolate) ligand, 2,2′-selenobis(4,6-di-tert-butylphenol), (H₂^ArOSeO).

Funder

U.S. Department of Homeland Security

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT01798F

Reference47 articles.

1. Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301

2. Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl62– (M = Ti, Zr, Hf, U) and UOCl5– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

3. Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

4. Carbon K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Examination of Metal–Carbon Bonding in Metallocene Dichlorides

5. Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations

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