A metal-free biaryl coupling reaction activated by a sulfonium salt-Reference-Cited by-同舟云学术

A metal-free biaryl coupling reaction activated by a sulfonium salt

Published:2018 Issue:22 Volume:5 Page:3219-3225
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Higuchi Kazuhiro¹²³^ORCID,Tago Takuhiro¹²³,Kokubo Yusuke¹²³,Ito Motoki¹²³^ORCID,Tayu Masanori¹²³^ORCID,Sugiyama Shigeo¹²³,Kawasaki Tomomi¹²³

Affiliation:

1. Meiji Pharmaceutical University

2. Tokyo 204-8588

3. Japan

Abstract

A metal-free biaryl coupling reaction of phenol or aryl ethers mediated by a sulfonium salt formed from diphenyl sulfoxide and trifluoromethanesulfonic anhydride has been developed. The method is a rapid, one-pot reaction, leaving no traces of the sulfonium moiety in the product.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00798E

Reference39 articles.

1. Aryl−Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction

2. Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

3. Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products