Kinetic <i>vs</i>. thermodynamic control of β-functionalized cyclic ketones: a theoretical investigation of regioselective formation of enolates-Reference-Cited by-同舟云学术

Kinetic vs. thermodynamic control of β-functionalized cyclic ketones: a theoretical investigation of regioselective formation of enolates

Published:2022 Issue:22 Volume:9 Page:6205-6212
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Petroselli Manuel¹^ORCID,Bacchiocchi Corrado²^ORCID

Affiliation:

1. Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, CH 8093 Zürich, Switzerland

2. School of Science and Technology, Chemistry Division, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy

Abstract

The reported theoretical study sheds light on the regioselective formation of enolates in β-functionalized ketones, highlighting the importance of non-covalent interactions.

Funder

Università degli Studi di Camerino

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01343F

Reference22 articles.

1. Michael Addition of Stannyl Ketone Enolate to α,β-Unsaturated Esters Catalyzed by Tetrabutylammonium Bromide and an ab Initio Theoretical Study of the Reaction Course

2. Michael Addition Reactions of Highly Basic Enolates for the Formation of 2‐(Tosylamino)Dihydrochalcones

3. Catalytic enantioselective aldol reactions

4. Enolate-Based Regioselective Anti-Beckmann C–C Bond Cleavage of Ketones

5. Tetrahedron report number 25

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