Acetylene and terminal alkyne complexes of copper(i) supported by fluorinated pyrazolates: syntheses, structures, and transformations

Author:

Parasar Devaborniny1234,Ponduru Tharun T.1234ORCID,Noonikara-Poyil Anurag1234ORCID,Jayaratna Naleen B.1234ORCID,Dias H. V. Rasika1234ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. The University of Texas at Arlington

3. Arlington

4. USA

Abstract

A variety of isolable, 2 : 1 and 1 : 1 copper(i)–alkyne complexes of containing pyrazolate ligand supports are presented as well as the copper pyrazolate mediated acetylenic C–H and alkyne CC bond functionalizations.

Funder

Welch Foundation

American Floral Endowment

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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