Quantifying electronic similarities between NHC–gold(i) complexes and their isolobal imidazolium precursors-Reference-Cited by-同舟云学术

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Quantifying electronic similarities between NHC–gold(i) complexes and their isolobal imidazolium precursors

Published:2019 Issue:28 Volume:21 Page:15615-15622
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Azofra Luis Miguel¹²³⁴⁵^ORCID,Veenboer Richard M. P.⁶⁷⁸⁹¹⁰^ORCID,Falivene Laura¹¹¹²¹³¹⁴,Vummaleti Sai V. C.¹¹¹²¹³¹⁴^ORCID,Poater Albert¹⁵¹⁶¹⁷⁵^ORCID,Nolan Steven P.¹⁸¹⁹²⁰²¹²²^ORCID,Cavallo Luigi¹¹¹²¹³¹⁴^ORCID

Affiliation:

1. CIDIA-FEAM (Unidad Asociada al Consejo Superior de Investigaciones Científicas, CSIC, avalada por el Instituto de Ciencia de Materiales de Sevilla, Universidad de Sevilla)

2. Instituto de Estudios Ambientales y Recursos Naturales (i-UNAT)

3. Universidad de Las Palmas de Gran Canaria (ULPGC)

4. Las Palmas de Gran Canaria

5. Spain

6. EaStCHEM

7. School of Chemistry

8. University of St Andrews

9. St Andrews

10. UK

11. King Abdullah University of Science and Technology (KAUST)

12. KAUST Catalysis Center (KCC)

13. Thuwal 23955-6900

14. Saudi Arabia

15. Institut de Química Computacional i Catàlisi

16. Departament de Química, Universitat de Girona

17. 17003 Girona

18. Department of Chemistry and Center for Sustainable Chemistry

19. Ghent University

20. 9000 Gent

21. Belgium

22. Department of Chemistry

Abstract

The σ and π donor/acceptor properties of the carbon–gold bond are manifested by changes in ¹⁹⁷Au spectroscopic data.

Funder

H2020 European Research Council

King Abdullah University of Science and Technology

Universidad de Las Palmas de Gran Canaria

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02844G

Reference65 articles.

1. A stable crystalline carbene

2. Direct Synthesis of a Mercury Salt-Carbene Complex

3. 1,3-Dimethyl-4-imidazolinyliden-(2)-pentacarbonylchrom ein neuer übergangsmetall-carben-komplex

4. Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding

5. Ruthenium-Based Olefin Metathesis Catalysts Bearing N-Heterocyclic Carbene Ligands

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